Role of compositional changes on thermal,magnetic,and mechanical properties of Fe-P-C-based amorphous alloys

This work aimed to tune the comprehensive properties of Fe-P-C-based amorphous system through investigating the role of microalloying process on the crystallization behavior,glass forming ability(GFA),soft magnetic features,and mechanical properties.Considering minor addition of elements into the system,it was found that the simultaneous microalloying of Ni and Co leads to the highest GFA,which was due to the optimization of compositional heterogeneity and creation of near-eutectic composition.Moreover,the FeCoNiCuPC amorphous alloy exhibited the best anelastic/viscoplastic behavior under the nanoindentation test,which was owing to the intensified structural fluctuations in the system.However,the improved plasticity by the extra Cu addition comes at the expense of magnetic properties,so that the saturation magnetization of this alloying system is significantly decreased compared to the FeCoPC amorphous alloy with the highest soft magnetic properties.In total,the results indicated that a combination of added elemental constitutes,i.e.,Fe69Co5Ni5Cu1P13C7 composition,provides an optimized state for the comprehensive properties in the alloying system.     

Transition-metal free synthesis of diaryl vinyl selenides: a simple synthetic approach with high selectivity

A simple, highly efficient synthetic protocol is developed for the synthesis of unsymmetrical diaryl vinyl selenides from diaryldiselenide and β-bromo styrene under transition-metal free conditions in N,N′-dimethyl propylene urea and 130 °C to afford high yields and excellent selectivities. This method provides a new strategy to fabricate a wide variety of important substituted molecular skeletons and an alternative to conventionally used metal salts, additives, and ligands.     

三功能策略设计制备具有优异低温抗积碳性能的Ni-CeO2@SiO2催化剂催化甲烷干重整反应

随着全球人为温室气体排放量(主要是甲烷和二氧化碳)的增加,全球变暖的趋势逐渐增加,因此,迫切需要通过各种技术来捕获和利用这些温室气体.甲烷干气重整反应(DRM)可以有效地将甲烷和二氧化碳这两种资源丰富、价格低廉的温室气体转化为高附加值化学品,减少它们向大气排放.尽管DRM工艺的应用具有许多优势,但是反应期间碳沉积和活性组分的烧结是阻碍其工业应用的两个主要原因.这些碳沉积物可能覆盖活性中心或阻塞催化剂的孔道,从而导致催化剂活性降低.镍基催化剂因其价格低廉、初始活性高和资源丰富而得到广泛的应用.但应用于DRM反应的Ni基催化剂在反应中容易烧结和积碳,导致催化剂迅速失活.为解决上述问题,本文从三功能策略角度出发,即SiO2壳层的限域作用和Ni-Ce之间的协同作用以及CeO2的消除积碳作用,采用原位一锅法设计合成了一种限域型Ni-CeO2核壳结构催化剂(Ni-CeO2@SiO2).通过X射线衍射、透射电子显微镜、能量色散X射线光谱、N2吸附/脱附、氢气程序升温还原和脱附、氧气程序升温脱附、拉曼光谱、热重分析和原位漫反射红外傅里叶变换光谱测试对催化剂进行了系统的表征,来揭示催化剂的理化性质和反应机理.催化剂应用于甲烷干气重整反应结果表明,在温度区间为550～800℃时,与传统浸渍法合成的催化剂相比,Ni-CeO2@SiO2催化剂具有更高的活性.高温800℃下的稳定性测试结果显示,传统浸渍法合成的催化剂在反应20 h后就出现了大量的积碳且活性下降明显;而Ni-CeO2@SiO2催化剂在800℃下反应100 h后未检测到积碳,并且催化剂中的Ni纳米颗粒的平均粒径从5.01 nm仅增长到5.77 nm,表现出很好的高温抗积碳和耐烧结性能.值得注意的是,Ni-CeO2@SiO2催化剂在低温600℃(形成碳沉积的最可能温度区域)下反应20h后也未检测到积碳的形成,表现出催化剂良好的低温稳定性和抗积碳性能.这可能归因于对Ni-CeO2@SiO2催化剂的三功能作用,即多孔二氧化硅壳层的限域作用、Ni与CeO2之间强的金属-金属氧化物相互作用以及具有丰富活性氧物种CeO2的消除积碳的作用.通过原位漫反射红外傅里叶变换光谱测试来探究反应机理.结果 表明,DRM反应在Ni-CeO2@SiO2催化剂上遵循L-H机理,添加CeO2可以消除碳沉积并促进CO2活化.该三功能策略为设计其他应用于DRM的高性能催化剂提供了指导,有望加快该工艺的工业化.     

各向异性本构关系在板料成形数值模拟中的应用

对几种能表达面内各向异性的屈服准则Hill、Barlat-Lian、Barlat进行了比较。以弹性变形服从各向同性广义虎克定律的情况下，给出了基于张量算法推导的弹塑性本构关系的一般表达式，并由此导出了相应屈服准则的弹塑性本构关系的显式表达。借助ABAQUS软件本构模块用户子程序接口，分别实现了这些屈服准则在ABAQUS的嵌入。以模拟方形盒的拉延过程为例，分析了不同的屈服准则在板料成形过程数值模拟中的应用。模拟结果表明，基于弹塑性本构关系一般表达所列出的相应屈服准则的显式表达式是正确的；在采用壳元来模拟板料成形时，采用Barlat准则的模拟结果和采用Barlat-Lian准则的结果差别不大。     

A quasi-flow constitutive model with strain-rate dependence

In this paper, the proposed is a quasi-flow constitutive model with strain-rate sensitivity for elastic plastic large deformation. The model is based on the Quasi-flow Corner theory, and is suitable for the sheet metal forming process simulation with a variable punch machine velocity. Uniaxial tensile tests and deep-drawing tests of a circular blank with square punch are carried out and numerically simulated. The consistency between the experimental and the numerically simulated results shows the validity of the present new constitutive model. The project supported by the Scientific Foundation of National Outstanding Youth of China (10125208), the National Natural Science Foundation of China (19832020), and the National Education Committee of China     

Plastic surface strain mapping of bent sheets by image correlation

A technique using a single CCD camera, a precision rotation/translation stage, a telecentric zoom lens, and digital image correlation software is described for measuring surface profiles and surface plastic strain distributions of a bent thin sheet. The measurement principles, based on both parallel and pinhole perspective projections, are outlined and the relevant mathematical equations for computing the profiles and displacement fields on a curved surface are presented. The typical optical setup as well as the experimental measurement and digital image correlation analysis procedure are described. The maximum errors in the in-plane and out-of-plane coordinates or displacements are about ±5 and ±25 μm, respectively, and the maximum errors in surface strain mapping are about 0.1% or less based on a series of evaluation tests on flat and curved sample surfaces over a physical field of view of 15.2 × 11.4 mm². As an application example, the shape and surface plastic strain distribution example, the shape and surface plastic strain distributions around a bent apex of a flat 2 mm thick automotive aluminum AA5182-O sheet, which underwent a 90° bend with three bend ratios of 2t, 1t, and 0.6t, are determined using the proposed technique.     

飞秒激光冲击AZ31B镁合金过程的数值模拟

采用有限元分析法对飞秒激光冲击AZ31B镁合金进行数值模拟,研究了激光冲击处理对镁合金变形过程的影响,分析了单脉冲激光冲击下材料内部的位移、动能、应力和应变的分布情况,得到了材料的瞬态速度和应变率变化过程.仿真结果表明,单脉冲飞秒激光冲击镁合金产生的塑性变形,可在材料表面形成微米级凹坑,中心点处最大位移为34μm,最大变形速度390m/s;在冲击初期,材料表面的应力和应变主要分布在冲击区域中心节点和边缘附近,并且得到镁合金的最大应力和最大应变率分别为955 MPa和1.8×106 s-1.研究结果能够为深入分析飞秒激光与镁合金作用时材料变形参量的变化规律提供数值理论依据.     

The least-squares meshfree method for rigid-plasticity with frictional contact

The least-squares meshfree method (LSMFM) for rigid-plasticity based on J₂-flow rule and infinitesimal theory is proposed. In the least-squares formulation the squared residuals of the constitutive and equilibrium equations are minimized. Those residuals are represented in a form of first-order differential system using the velocity and stress components as nodal unknowns and thus the proposed formulation is a mixed-type method. Also the penalty scheme for the enforcement of the boundary and frictional contact conditions is devised and the reshaping of nodal supports is introduced to avoid the difficulties due to the severe local deformation near the contact interface. The proposed method does not require any structure of extrinsic cells for the construction of shape functions, the treatment of incompressibility, the integration of variational formulation and the reconstruction of approximation. Through some numerical examples of metal forming processes, the validity and effectiveness of the method are discussed.     

爆炸成型弹丸贯穿混凝土的实验研究

介绍几种聚能装药对混凝土层的破坏效果，并对聚能装药的结构设计与破坏效果的相互关系进行了分析与讨论。文中重点对截卵形药型罩、亚半球变壁厚药型罩、双功能药型罩的装药结构、破甲能力及目标结构特性进行了研究。     

Numerical analysis of diffuse and localized necking in orthotropic sheet metals

In the present paper the diffuse and localized necking models according to Swift [Swift, H.W., 1952. Plastic instability under plane stress, Journal of the Mechanics and Physics of Solids, 11–18], Hill [Hill, R., 1952. On discontinuous plastic states, with special reference to localized necking in thin sheets. Journal of the Mechanics and Physics of Solids 1, 19–30] and Marciniak and Kuczyński [Marciniak, Z., Kuczyński, K., 1967. Limit strains in the process of stretch-forming sheet metal. International Journal of Mechanical Sciences 9, 609–620], respectively, are considered. A theoretical framework for the mentioned models is proposed that covers rigid–plastic as well as elastic–plastic constitutive modelling using various advanced phenomenological yield functions that are able to account very accurately for plastic anisotropy. The mentioned necking models are applied to different orthotropic sheet metals in order to assess their predictive capabilities and to stress out some potential sources for discrepancies between simulations and experiments. In particular, the impact of the applied hardening curve and the equibiaxial r-value, which was recently introduced by Barlat [Barlat, F., Brem, J.C., Yoon, J.W., Chung, K., Dick, R.E., Choi, S.-H., Pourboghrat, F., Chu, E., Lege, D.J., 2003. Plane stress yield function for aluminium alloy sheets – part 1: theory. International Journal of Plasticity 19, 297–1319], on formability prediction is investigated. Furthermore, the impact of the Portevin–LeChatelier effect on the formability of aluminum sheet metals is discussed.